粘结长度
钙钛矿(结构)
催化作用
材料科学
半径
原子半径
选择性
分子几何学
结晶学
无机化学
化学
晶体结构
分子
有机化学
计算机安全
计算机科学
作者
Mingfa Chen,Kuan Chang,Zhengkun Yu,Zhenbao Zhang,Yuming Dong,Xiaoyu Qiu,Heqing Jiang,Yongfa Zhu,Jun Zhu
标识
DOI:10.1002/anie.202312433
摘要
Sn-based perovskite oxides have shown intriguing potential in CO2 electroreduction. In their Research Article (e202305530), Jiawei Zhu and co-workers report an effective strategy to promote CO2-to-HCOOH conversion of Sn-based perovskite oxides by A-site-radius-controlled Sn−O bond lengths. With Ba1−xSrxSnO3 (x from 0 to 1) series as proof-of-concept catalysts, it is demonstrated that their activity/selectivity for HCOOH featured a volcano-type dependence on the Sn−O bond lengths, with a maximum point corresponding to Ba0.5Sr0.5SnO3.
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