Directly Sputtered Molybdenum Disulfide Nanoworms Decorated with Binder-less VN and W2N Nanoarrays for Bendable Large-Scale Asymmetric Supercapacitor

Considering the superior capacitive performance and rich redox kinetics, the two-dimensional (2D) layered molybdenum disulfide (MoS2) and transition metal nitrides (TMNs) have emerged as the latest set of nanomaterials. Direct incorporation of key materials vanadium nitride (VN) and tungsten nitride (W2N) into a MoS2 array has been achieved on cost-effective, bendable stainless steel (SS) foil via a reactive cosputtering route. Herein, we have utilized the synergistic effect of intermixed nanohybrids to develop a flexible asymmetric supercapacitor (FASC) device from MoS2–VN@SS (negative) and MoS2–W2N@SS (positive) electrodes. As-constructed FASC cell possesses a maximum operational potential of 1.80 V and an exceptional gravimetric capacitance of 200 F g–1 at a sweep rate of 5 mV s–1. The sustained capacitive performance mainly accounts for the synergism induced through unique interfacial surface architecture provided by MoS2 nanoworms and TMN conductive hosts. The sulfur and nitrogen edges ensure the transport channels to Li+/SO4–2 ions for intercalation/deintercalation into the composite nanostructured thin film, further promoting the pseudocapacitive behavior. Consequently, the supercapacitor cell exhibits a distinctive specific energy of 87.91 Wh kg–1 at 0.87 kW kg–1 specific power and a reduced open circuit potential (OCP) decay rate (∼42% self-discharge after 60 min). Moreover, the assembled flexible device exhibits nearly unperturbed electrochemical response even at bending at 165° angle and illustrates a commendable cyclic life-span of 82% after 20,000 charge–discharge cycles, elucidating advanced mechanical robustness and capacitance retentivity. The powering of a multicolor light-emitting diode (LED) and electronic digital watch facilitates the practical evidence to open up possibilities in next-generation state-of-the-art wearable and miniaturized energy storage systems.