Mass Budget of Mercury (Hg) in the Seawater of Eastern China Marginal Seas: Importance of the Sediment–Water Transport Processes

The Eastern China Marginal Seas (ECMS) have been facing a variety of environmental problems, including mercury (Hg) pollution. Although several previous studies have been focused on mass balance of Hg in the ECMS, the contribution of Hg transport at the sediment-water interface remains unclear. This study was aimed to access and quantify the importance of sediment-water transport processes in Hg cycling. Significantly positive correlations were observed between Hg concentrations in the overlying and bottom water and the diffusion rates of Hg from sediment to the water. Approximately 2-3 times higher of THg concentrations in the entire water column were observed in a winter cruise with strong waves which was supposed to strengthen the resuspension process. The mass budget of Hg in the ECMS further showed that diffusion and resuspension processes accounted for approximate 46%, 60%, and 16% of total input Hg in the BS, YS, and ECS, respectively. These results suggest that the sediment-water transport processes play an important role in Hg cycling in the ECMS. As an important "pool" of Hg in the ECMS, the transport of Hg at the sediment-water interface may affect the long-term risk assessment of Hg in these systems.