闪烁
空格(标点符号)
X射线
纳米技术
化学
物理
材料科学
核物理学
光学
计算机科学
操作系统
探测器
作者
Tianhao Chen,Xu Ye,Ying Ao,Chuluo Yang,Qianqian Lin,Shaolong Gong
标识
DOI:10.1002/ange.202401833
摘要
Organic scintillators have recently attracted growing attention for X‐ray detection in industrial and medical applications. However, these materials still face critical obstacles of low attenuation efficiency and/or inefficient triplet exciton utilization. Here we developed a new category of organogold(III) complexes, Tp‐Au‐1 and Tp‐Au‐2, through adopting a through‐space interaction motif to realize high X‐ray attenuation efficiency and efficient harvesting of triplet excitons for emission. Thanks to the efficient through‐space charge transfer process, this panel of complexes achieved higher photoluminescence quantum yield and shorter radiative lifetimes compared with the through‐bond reference complexes. Inspiringly, these organogold(III) complexes exhibited polarity‐dependent emission origins: thermally activated delayed fluorescence and/or phosphorescence. Under X‐ray irradiation, Tp‐Au‐2 manifested intense radioluminescence together with a record‐high scintillation light yield of 77,600 photons MeV‐1 for organic scintillators. The resulting scintillator screens demonstrated high‐quality X‐ray imaging with >16.0 line pairs mm–1 spatial resolution, outstripping most organic and inorganic scintillators. This finding provides a feasible strategy for the design of superior organic X‐ray scintillators.
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