Specific Hydrogen Spillover Pathways Generated on Graphene Oxide Enabling the Formation of Non‐Equilibrium Alloy Nanoparticles

The phenomenon of hydrogen spillover is investigated as a means of realizing a hydrogen-based society for over half a century. Herein, a graphene oxide having a precisely tuned architecture via calcination in air to introduce ether groups onto basal planes along with carbon defects is reported. This material provides specific pathways for the spillover of atomic hydrogen and has practical applications with regard to the synthesis of non-equilibrium solid-solution alloy nanoparticles. A combination of experimental work and simulations confirmed that the presence of ether groups associated with carbon defects facilitated hydrogen spillover within the basal planes of this graphene oxide. This enhanced hydrogen spillover ability, in turn, enables the simultaneous reduction of Ru