材料科学
锂(药物)
阴极
电化学
降级(电信)
阳极
涂层
化学工程
晶间腐蚀
杂质
扩散
镍
电极
复合材料
冶金
热力学
物理化学
微观结构
化学
有机化学
工程类
内分泌学
医学
电信
物理
计算机科学
作者
Youqi Chu,Yongbiao Mu,Lingfeng Zou,Yan Hu,Jie Cheng,Buke Wu,Meisheng Han,Shibo Xi,Qing Zhang,Lin Zeng
标识
DOI:10.1002/adma.202212308
摘要
Pushing the limit of cutoff potentials allows nickel-rich layered oxides to provide greater energy density and specific capacity whereas reducing thermodynamic and kinetic stability. Herein, a one-step dual-modified method is proposed for in situ synthesizing thermodynamically stable LiF&FeF3 coating on LiNi0.8 Co0.1 Mn0.1 O2 surfaces by capturing lithium impurity on the surface to overcome the challenges suffered. The thermodynamically stabilized LiF&FeF3 coating can effectively suppress the nanoscale structural degradation and the intergranular cracks. Meanwhile, the LiF&FeF3 coating alleviates the outward migration of Oα- (α<2), increases oxygen vacancy formation energies, and accelerates interfacial Li+ diffusion. Benefited from these, the electrochemical performance of LiF&FeF3 modified materials is improved (83.1% capacity retention after 1000 cycles at 1C), even under exertive operational conditions of elevated temperature (91.3% capacity retention after 150 cycles at 1C). This work demonstrates that the dual-modified strategy can simultaneously address the problems of interfacial instability and bulk structural degradation and represents significant progress in developing high-performance lithium-ion batteries (LIBs).
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