Catalysis of Alloys: Classification, Principles, and Design for a Variety of Materials and Reactions

Alloying has long been used as a promising methodology to improve the catalytic performance of metallic materials. In recent years, the field of alloy catalysis has made remarkable progress with the emergence of a variety of novel alloy materials and their functions. Therefore, a comprehensive disciplinary framework for catalytic chemistry of alloys that provides a cross-sectional understanding of the broad research field is in high demand. In this review, we provide a comprehensive classification of various alloy materials based on metallurgy, thermodynamics, and inorganic chemistry and summarize the roles of alloying in catalysis and its principles with a brief introduction of the historical background of this research field. Furthermore, we explain how each type of alloy can be used as a catalyst material and how to design a functional catalyst for the target reaction by introducing representative case studies. This review includes two approaches, namely, from materials and reactions, to provide a better understanding of the catalytic chemistry of alloys. Our review offers a perspective on this research field and can be used encyclopedically according to the readers' individual interests.