材料科学
光催化
异质结
纳米复合材料
铋铁氧体
化学工程
铁氧体(磁铁)
蚀刻(微加工)
可见光谱
制作
催化作用
铋
光化学
复合数
纳米技术
复合材料
光电子学
化学
冶金
有机化学
工程类
电介质
多铁性
病理
替代医学
医学
图层(电子)
铁电性
作者
Qi Zhang,Jiabin Liu,Lang Chen,Chen-Xi Xiao,Peng Chen,Sheng Shen,Jinsong Guo,Chak Tong Au,Shuang‐Feng Yin
标识
DOI:10.1016/j.apcatb.2019.118529
摘要
Among MOFs, the Fe-based ones (such as MIL-53(Fe)) show impressive visible light response due to the extensive presence of Fe-O clusters, but their photo-activities are often restrained by severe recombination of electron-hole pairs. To circumvent this limitation, we developed an in-situ etching-and-regrowth strategy for the fabrication of heterojunctions. Through the partial destruction of the external surface of a 3D MIL-53(Fe) bipyramid, we generated bismuth ferrite (BFO) nanosheets on its surface. The rough surface of the as-fabricated composite is beneficial for light absorption as well as enlargement of specific surface area and exposure of active sites. Furthermore, the interfaces between MIL-53(Fe) and BFO accelerate the separation and transfer of charge carriers owing to the co-presence of FeO bonds in both components. The obtained composites show outstanding catalytic activity as well as excellent stability for the selective oxidation of benzyl alcohols to the corresponding aldehydes under visible light irradiation.
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