Highly Efficient Alkaline Water Splitting with Ru‐Doped Co−V Layered Double Hydroxide Nanosheets as a Bifunctional Electrocatalyst

-based electrolyzer and many other bifunctional electrocatalyst-based ones. The incorporation of Ru changes the morphology of the resultant nanosheets to offer high electrochemical surface areas for electrocatalysis; at the same time, it significantly boosts the intrinsic HER/OER electrocatalytic activity. For HER, the energy barrier of the Volmer step is efficiently reduced upon Ru doping, whereas the Ru dopants optimize the absorption strength of *O intermediates to facilitate the OER process. This work offers a feasible means to optimize the Co-based hydroxide materials for improved electrocatalysis in overall water splitting.