Fabrication of hierarchical SrTiO 3 @MoS 2 heterostructure nanofibers as efficient and low-cost electrocatalysts for hydrogen-evolution reactions

The construction of low-cost, high-performance electrocatalysts instead of platinum catalysts is critical to solving the energy crisis. Here, using simple electrospinning and hydrothermal methods, new MoS₂ nanosheets on SrTiO₃ nanofibers (NFs) and 2D SrTiO₃@MoS₂ heterostructure NFs are synthesized. In addition, SrTiO₃@MoS₂ heterostructure NFs are compared with bare SrTiO₃ NFs and MoS₂ nanosheets. Importantly, the prepared SrTiO₃@MoS₂ heterostructure shows better hydrogen-evolution reaction performance than other MoS₂-based electrocatalysts with an overpotential of 165 mV at 10 mA cm^-2, a Tafel slope of 81.41 mV dec^-1, and long-term electrochemical durability of 3000 cycles. Therefore, the present work strongly demonstrates the positive synergy between SrTiO₃ NFs and layered MoS₂, and also provides a strategy for preparing low-cost and high-activity water-decomposition electrocatalysts.