硝化作用
化学
区域选择性
部分
硝基
硝基化合物
金属
组合化学
有机化学
催化作用
烷基
作者
Ying Zhang,Wenyan Dan,Xiaoying Fang
出处
期刊:Organometallics
[American Chemical Society]
日期:2017-04-20
卷期号:36 (9): 1677-1680
被引量:39
标识
DOI:10.1021/acs.organomet.7b00120
摘要
A regioselective nitration of BN-substituted arene compounds has been successfully developed. The first examples of BN-nitroarenes have been synthesized and structurally characterized by X-ray diffraction analysis. Photophysical studies of these novel compounds reveal an effective π conjugation between the nitro group and 1,2-azaborine moiety in the solution phase. A plausible mechanism for this nitration reaction is proposed.
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