Tailorable Dynamics in Nonlinear Optical Metasurfaces

Abstract Controlling light with light is essential for all‐optical switching, data processing in optical communications and computing. Until now, all‐optical control of light has relied almost exclusively on nonlinear optical interactions in materials. Achieving giant nonlinearities under low light intensity is essential for weak‐light nonlinear optics. In the past decades, such weak‐light nonlinear phenomena have been demonstrated in photorefractive and photochromic materials. However, their bulky size and slow speed have hindered practical applications. Metasurfaces, which enhance light–matter interactions at the nanoscale, provide a new framework with tailorable nonlinearities for weak‐light nonlinear dynamics. Current advances in nonlinear metasurfaces are introduced, with a special emphasis on all‐optical light controls. The tuning of the nonlinearity values using metasurfaces, including enhancement and sign reversal is presented. The tailoring of the transient behaviors of nonlinearities in metasurfaces to achieve femtosecond switching speed is also discussed. Furthermore, the impact of quantum effects from the metasurface on the nonlinearities is introduced. Finally, an outlook on the future development of this energetic field is offered.