化学
烯丙基重排
合成子
催化作用
喹啉
组合化学
砜
二甲基乙酰胺
有机化学
溶剂
作者
Fuhong Xiao,Chao Liu,Shanshan Yuan,Huawen Huang,Guo‐Jun Deng
标识
DOI:10.1021/acs.joc.8b01486
摘要
An efficient strategy for the preparation of allylic sulfones has been developed. In this protocol, readily available 2-methylquinolines or 2-methylbenzothiazoles, sodium sulfinates, and dimethylacetamide (DMA) were successfully assembled under user-friendly iron catalysis, and DMA provided two carbons as a dual synthon. A broad range of functionalized heterocyclic allylic sulfones were accessed with a wide functional group tolerance.
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