脱羧
亲核细胞
碳纤维
化学
结合
增强碳-碳
有机化学
羧酸
组合化学
光化学
催化作用
材料科学
复合数
数学
数学分析
复合材料
作者
David M Kitcatt,Simon M. Nicolle,Ai‐Lan Lee
摘要
The quest to find milder and more sustainable methods to generate highly reactive, carbon-centred intermediates has led to a resurgence of interest in radical chemistry. In particular, carboxylic acids are seen as attractive radical precursors due their availability, low cost, diversity, and sustainability. Moreover, the corresponding nucleophilic carbon-radical can be easily accessed through a favourable radical decarboxylation process, extruding CO2 as a traceless by-product. This review summarizes the recent progress on using carboxylic acids directly as convenient radical precursors for the formation of carbon-carbon bonds via the 1,4-radical conjugate addition (Giese) reaction.
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