共价键
离子键合
材料科学
共价有机骨架
膜
离子电导率
质子
侧链
导电体
离子
电导率
纳米技术
化学工程
高分子化学
化学
聚合物
有机化学
物理化学
电极
复合材料
电解质
工程类
物理
量子力学
生物化学
作者
Benbing Shi,Xiao Pang,Bohui Lyu,Hong Wu,Jianliang Shen,Jingyuan Guan,Xiaoyao Wang,Chunyang Fan,Li Cao,Tianhao Zhu,Yan Kong,Yawei Liu,Zhongyi Jiang
标识
DOI:10.1002/adma.202211004
摘要
Side-chain engineering of covalent organic frameworks as advanced ion conductors is a critical issue to be explored. Herein, ionic covalent organic framework membranes (iCOFMs) with spacer-engineered ionic channel are de novo designed and prepared. The ionic channels are decorated with side chains comprising spacers having different carbon chain lengths and the -SO3 H groups at the end. Attributed to the synergistic contribution from the spacers and the -SO3 H groups, the iCOFM with moderate-length spacer exhibit the highest through-plane proton conductivity of 889 mS cm-1 at 90 °C.
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