双功能
磷化氢
化学
胺气处理
合作性
烷基化
催化作用
配体(生物化学)
组合化学
有机化学
生物化学
受体
作者
Arnab Rit,Biswaranjan Boity,Misba Siddique
摘要
Newly developed amine functionalized NHC-supported CoIII-complexes have been identified as highly effective bifunctional catalysts for the α-alkylation of nitriles using a plethora of alcohols, ranging from aliphatic to aromatic and intriguingly, also secondary ones. Comparison of their activities with the non-bifunctional analogues uncovered their extremely high activities although possessing the high-valent CoIII-center due to metal-ligand cooperativity, which has been established by an array of control experiments.
科研通智能强力驱动
Strongly Powered by AbleSci AI