质子化
化学
质子
自旋态
金属
光谱学
协调球
配位复合体
核磁共振波谱
光化学
分析化学(期刊)
结晶学
无机化学
立体化学
离子
有机化学
物理
量子力学
作者
Conor T. Kelly,Sean Dunne,Irina A. Kühne,A. S. Barker,Kane Esien,Solveig Felton,Helge Müller‐Bunz,Yannick Ortin,Grace G. Morgan
标识
DOI:10.1002/anie.202217388
摘要
Abstract Reversible proton‐induced spin state switching of an Fe III complex in solution is observed at room temperature. A reversible magnetic response was detected in the complex, [Fe III (sal 2 323)]ClO 4 ( 1 ), using Evans’ method 1 H NMR spectroscopy which indicated cumulative switching from low‐spin to high‐spin upon addition of one and two equivalents of acid. Infrared spectroscopy suggests a coordination‐induced spin state switching (CISSS) effect, whereby protonation displaces the metal‐phenoxo donors. The analogous complex, [Fe III (4‐NEt 2 ‐sal 2 323)]ClO 4 ( 2 ), with a diethylamino group on the ligand, was used to combine the magnetic change with a colorimetric response. Comparison of the protonation responses of 1 and 2 reveals that the magnetic switching is caused by perturbation of the immediate coordination sphere of the complex. These complexes constitute a new class of analyte sensor which operate by magneto‐modulation , and in the case of 2 , also yield a colorimetric response.
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