Compression Damage Precursors of Silane-Protected Concrete Under Sulfate Erosion Based on Acoustic Emission Characterization

Concrete materials exposed to sulfate-rich geological environments are prone to structural durability degradation due to chemical erosion. Silane-based protective materials can enhance the durability of concrete structures under harsh environmental conditions. This study investigates the evolution of acoustic emission (AE) precursor characteristics in silane-protected, sulfate-eroded concrete specimens during uniaxial compression failure. Unlike existing research focused primarily on protective material properties, this work establishes a novel framework linking “silane treatment–AE parameters–failure precursor identification”, thereby bridging the research gap in damage evolution analysis of sulfate-eroded concrete under silane protection. Uniaxial compressive strength tests and AE monitoring were conducted on both silane-protected and unprotected sulfate-eroded concrete specimens. A diagnostic system integrating dynamic analysis of the acoustic emission b-value, mutation detection of energy concentration index ρ, and multifractal detrended fluctuation analysis (MF-DFA) was developed. The results demonstrate that silane-protected specimens exhibited a distinct b-value escalation followed by an abrupt decline prior to peak load, whereas unprotected specimens showed disordered fluctuations. The mutation point of energy concentration ρ for silane-protected specimens occurred at 0.83 σc, representing a 9.2% threshold elevation compared to 0.76 σc for unprotected specimens, confirming delayed damage accumulation in protected specimens. MF-DFA revealed narrowing spectrum width (∆α) in unprotected specimens, indicating reduced heterogeneity in AE signals, while protected specimens maintained significant multifractal divergence. ∆fα peak localization revealed that weak AE signals dominated during early loading stages in both groups, with crack evolution primarily involving sliding and friction. During the mid-late elastic phase, crack propagation became the predominant failure mode. Experimental evidence confirms the engineering significance of silane protection in extending service life of concrete structures in sulfate environments. The proposed multi-parameter AE diagnostic methodology provides quantitative criteria for the safety monitoring of protected concrete structures in sulfate-rich conditions.