This study investigates the mechanical behavior of a new type of link slab through experimental testing and numerical simulation. A full-scale segmental specimen of an I-shaped steel–concrete composite beam was designed, and a vertical active plus horizontal follow-up loading system was employed to realistically simulate the stress state of the link slab. In parallel, a nonlinear finite element model was established in ABAQUS to validate and extend the experimental findings. Test results indicate that the link slab exhibits favorable static performance with a ductile flexural tensile failure mode. At ultimate load, tensile reinforcement yielded while compressive concrete remained uncrushed, demonstrating high safety reserves. Cracks propagated primarily in the transverse direction, showing a typical flexural tensile cracking pattern. The maximum crack width was limited to 0.4 mm and remained confined within the link slab region, which is beneficial for long-term durability, maintenance, and repair. The FE model successfully reproduced the experimental process, accurately capturing both the crack development and the ultimate bending capacity of the slab. The findings highlight the reliability of the proposed structural system, demonstrate that maximum crack width can be evaluated as an eccentric tension member, and confirm that bending capacity may be assessed using existing design specifications.