Ex situ synthesis of MOF@PET/cotton textile fibers as potential antibacterial materials

Abstract There is considerable scientific literature on MOF-based antibacterial textiles, especially with in situ methodologies for their synthesis. On the contrary, the ex situ synthesis of MOFs on fabrics has been little explored. Although, the latter may have more significant advantages when the expectation is to scale up the process industrially. The present study describes the synthesis of ex situ obtained MOF-199 and MOF-UiO-66-NH 2 onto carboxylated polyester/cotton (PETco) textile fibers and their preliminary-qualitative analysis as potential antibacterial textiles. For this, free synthesized MOFs were anchored on a previously carboxylated PETco fiber, using conditions that seek the formation of coordination bonds between the carboxyl groups of the fiber and the metal in the MOF. After soxhlet purification with water and methanol for more than 48 h, analysis by FTIR-ATR and XRD shows the superposition of signals typical of the fiber and the MOF, resembling what was previously reported for cotton-MOF systems. XPS showed 4.47% Cu, with Cu–O-C interactions for MOF-199@PETco, and 12.06% Zr, with Zr-O-C interactions for MOF UiO-66-NH 2 @PETco. Results corroborated by the SEM micrographs, which show the expected morphology for MOF-199, and homogeneously distributed MOF UiO-66-NH 2 crystals when they are anchored to the fiber.