聚苯胺
材料科学
纳米壳
纳米技术
储能
纳米线
柔性电子器件
电极
阴极
锌
催交
复合材料
纳米颗粒
化学
冶金
聚合物
物理化学
功率(物理)
工程类
聚合
系统工程
物理
量子力学
作者
Na Li,Zhidong Hou,Shiyu Liang,Yunjing Cao,Huanyan Liu,Wei Hua,Chunguang Wei,Feiyu Kang,Jian‐Gan Wang
标识
DOI:10.1016/j.cej.2022.139408
摘要
Flexible electrode materials are of critical importance for advancing the development of flexible Zn-MnO2 rechargeable batteries. However, the slow electron-transfer kinetics and poor structural stability of MnO2 dramatically impede their real-world practices. In this work, we showcase an in situ interfacial fabrication of a highly flexible MnO2@polyaniline (MnO2@PANI) core–shell nanowire film for high-rate and durable zinc energy storage. The conducting polyaniline nanoshell is of grand benefit for expediting the reaction kinetics and stabilizing the electrode. The MnO2@PANI hybrid cathode affords an impressive reversible capacity of 342 mA h g−1 at 0.2 A/g, and more notably, warrants substantially improved rate and cycling performance. The excellent zinc energy storage is further demonstrated in a flexible device. This encouraging achievement will pave a fresh design roadway for expediting the Zn-MnO2 technology toward smart and flexible electronics.
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