光催化
吸附
罗丹明B
化学工程
异质结
材料科学
氧化物
环境修复
比表面积
水溶液
光化学
降级(电信)
催化作用
无机化学
化学
有机化学
污染
冶金
工程类
生物
生态学
电信
光电子学
计算机科学
作者
Jianjun Li,Cuicui Tian,Hui Zhao,Jian Mei,Jian Zhang,Shijian Yang
标识
DOI:10.1016/j.jallcom.2019.151885
摘要
The development of low-cost and efficient photocatalysts is pursued to promote the large-scale application of photocatalysis in environmental remediation. In this study, cost-effective g-C3N4-RP (red phosphorus) heterostructures were controllably fabricated, in which sodium hypophosphite was utilized as a new phosphorus source. The formed RP exhibited a particle morphology with the size of 60–100 nm. These nanoparticles were strongly bonded to the g-C3N4 surface by forming P-N chemical bonds. When compared with pristine g-C3N4, the as-synthesized g-C3N4-RP hybrids exhibited synergistically improved adsorption and photocatalytic activity for the removal of Rhodamine B (RhB) pollutant in aqueous solution. The improved adsorption for g-C3N4-RP resulted from the higher surface area, presence of the manufactured larger delocalized system, and more negatively charged surface when RP was introduced. Meanwhile, the improved performance of the photocatalysis was a result of the strengthened light adsorption, improved separation and transfer of photogenerated electron-hole pairs, and efficient surface reaction. A typical Type II heterostructure was confirmed to be formed at the interface to accelerate the charge carrier transfer between g-C3N4 and RP. The h+ and •O2⁻ radicals were determined to be the major oxide species for RhB degradation. Finally, a possible RhB degradation mechanism was revealed in the g-C3N4-RP photocatalytic system. We believe that this study is of importance to accelerate the development of low-cost and effective catalysts for wastewater remediation by photocatalysis.
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