电解质
材料科学
电化学
锂(药物)
阳极
介电谱
阴极
快离子导体
相(物质)
电导率
电池(电)
箔法
化学工程
离子电导率
锂电池
金属
离子
无机化学
电极
化学
复合材料
冶金
物理化学
离子键合
热力学
功率(物理)
有机化学
医学
内分泌学
工程类
物理
作者
Jiajia Tan,Ashutosh Tiwari
出处
期刊:Electrochemical and Solid State Letters
[The Electrochemical Society]
日期:2012-01-01
卷期号:15 (3): A37-A37
被引量:52
摘要
We report the synthesis of high-quality cubic-phase Li7La3Zr2O12 powders using a solution based technique. Detailed structural, morphological, compositional and electrochemical characterization of the samples was performed. The lithium-ion conductivity of the cubic-phase Li7La3Zr2O12, determined by electrochemical impedance spectroscopy, was ∼1.67×10−4 S/cm. A proto-type all-solid-state battery with Li7La3Zr2O12 as electrolyte, LiCoO2 as cathode and a Lithium metal foil as anode was assembled. The cell was rechargeable and exhibited a very promising specific discharge capacity of 3.4 mAh/g which corresponds to 2.5% of the theoretical capacity. The above value is the highest discharge capacity reported till date using Li7La3Zr2O12 electrolyte.
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