铜
苯并咪唑
循环伏安法
材料科学
X射线光电子能谱
电极
聚合物
无机化学
阳极
电化学
分析化学(期刊)
化学
化学工程
冶金
物理化学
复合材料
有机化学
工程类
作者
Gi Xue,Jun Ding,Peiyi Wu,Gending Ji
出处
期刊:Journal of electroanalytical chemistry and interfacial electrochemistry
[Elsevier]
日期:1989-10-01
卷期号:270 (1-2): 163-173
被引量:32
标识
DOI:10.1016/0022-0728(89)85034-x
摘要
The effects of the pretreatment of copper in benzimidazole solutions on the anodic reactions have been observed. The structures of the chemisorbed benzimidazole on copper were studied by using the infrared reflection-absorption technique and X-ray photoelectron spectroscopy. It was found that a compact film of benzimidazolato copper(I) was formed on the copper surface when copper was immersed in a stirred benzimidazole solution and cyclic voltammetry applied. This compact polymer film inhibited anodic oxidation effectively.
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