卤化物
四方晶系
钙钛矿(结构)
金属卤化物
无辐射复合
重组
辐射传输
材料科学
极化(电化学)
金属
化学物理
电场
化学
结晶学
物理
无机化学
光学
晶体结构
物理化学
量子力学
生物化学
冶金
基因
作者
Wei Qin,Wajid Ali,Jianfeng Wang,Yong Liu,Xiaolan Yan,Pengfei Zhang,Zhaochi Feng,Hao Tian,Yanfeng Yin,Wenming Tian,Can Li
标识
DOI:10.1038/s41467-023-35837-1
摘要
Abstract The low fraction of non-radiative recombination established the foundation of metal halide perovskite solar cells. However, the origin of low non-radiative recombination in metal halide perovskite materials is still not well-understood. Herein, we find that the non-radiative recombination in twinning-tetragonal phase methylammonium lead halide (MAPbI x Cl 3-x ) is apparently suppressed by applying an electric field, which leads to a remarkable increase of the open-circuit voltage from 1.12 V to 1.26 V. Possible effects of ionic migration and light soaking on the open-circuit voltage enhancement are excluded experimentally by control experiments. Microscopic and macroscopic characterizations reveal an excellent correlation between the ferroelastic lattice deformation and the suppression of non-radiative recombination. The calculation result suggests the existence of lattice polarization in self-stabilizable deformed domain walls, indicating the charge separation that facilitated by lattice polarization is accountable for the suppressed non-radiative recombination. This work provides an understanding of the excellent performance of metal halide perovskite solar cells.
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