In situ facile synthesis and antibacterial activity of Ag-MOFs/cellulose filter paper composites for fruit fresh-keeping

A large number of fresh fruits are wasted in the supply chain due to spoilage, so it is crucial to develop fruit preservation materials. Herein, two novel Ag-MOFs/carboxymethyl filter paper (Ag-MOFs/CMFP) composites were successfully synthesized by in situ facile synthesis, which can be used as packaging materials to delay fruit spoilage. The synthesis process is simple and environmentally friendly, and the reaction conditions are mild. The mechanical property, water stability, and antibacterial activity of the as-synthesized Ag-MOFs/CMFP composites were investigated. Specifically, the composites exhibited high mechanical performance and the tensile strength was >10.00 MPa. Moreover, the composites displayed good water stability and can remain stable in water environment for >7 days, which can be attributed to the strong interaction between Ag-MOFs and CMFP. Significantly, Ag-MOF particles endow the composite papers with excellent antibacterial activity, which can inactivate 99.9 % of the bacteria. Attributed to these characteristics, these composite papers were used as fruit fresh-keeping materials and can prolong the shelf-life of cherry tomatoes and peaches for >10 days. This research not only provides a facile synthesis strategy for the flexible MOFs paper, but also provides instructive guidance for related research on fruit preservation materials.