纳米片
兴奋剂
材料科学
空位缺陷
Atom(片上系统)
三聚氰胺
光催化
结晶学
分析化学(期刊)
纳米技术
化学
有机化学
催化作用
光电子学
计算机科学
嵌入式系统
复合材料
作者
Junpeng Cui,Fucheng Yu,Jianbin Zhang,Xianxi Tang,Yangshuo Liu
标识
DOI:10.1016/j.optmat.2023.113777
摘要
S and O elements doped g-C3N4 nanosheets samples were prepared by calcinating the supramolecular precursor obtained by self-assembly of melamine and cyanuric acid by one-step double crucible method. In the O/S single-element doped sample, doping narrows the layer spacing of g-C3N4. While in the S, O co-doped sample, the phenomenon disappears due to the compensation effect of S and O atoms in adjacent layers. In the g-C3N4 sample doped with O/S single element, the O atom replaces the N atom of sp2 hybrid, and the S atom replaces the C atom of sp2 hybrid. In the S, O co-doped sample, the O atom replaces the N atom of sp2 hybrid, while the S atom replaces the C atom of sp2 hybrid, which greatly increases the electron concentration. The 3 d orbitals of S atoms in the co-doped g-C3N4 sample act as both donor and acceptor levels, contributing to the separation of photo-generated electrons and holes. Therefore, the S, O co-doped g-C3N4 sample shows the best photocatalytic performance.
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