Mesoporous carbon material prepared from sewage sludge hydrochar using Pluronic F127 as template for efficient removal of phenolic compounds: Experimental study and mechanism interpretation via advanced statistical physics model

Mesoporous carbon material (MCM) with rich ether surface group was prepared from sewage sludge hydrochar using Pluronic F127 as template under pyrolysis activation, which provided an energy-efficient method to promote the resource utilization of sewage sludge as adsorbents for phenols removal from water. The MCM possessed high surface area (549 m2/g), abundant mesopores (average width 3.81 nm) and well-developed graphite structure. Acidic conditions and low temperatures favored the adsorption of phenolic compounds. The quick adsorption process of reaching over 85% of the capacity in the first 10 min and intraparticle diffusion as primary rate-limiting step were observed for all phenolic compounds. Advanced statistical physics analysis was used successfully to interpret the adsorption mechanism of phenols onto MCM and revealed a multi-molecular monolayer adsorption process primarily through negative charge-assisted hydrogen bond interaction where the ether functional group contributed to the predominant active sites. The adsorption capacity of phenolic compounds depended upon the number of molecules adsorbed per ether active site and the available density of ether bond group on the surface of MCM. 2,4,6-trichlorophenol showed a highest adsorption priority to occupy the limited ether active sites and its adsorption capacity reached 0.49 mmol/g, while p-nitrophenol exhibited a maximum number of molecules adsorbed on the single ether active site, showing an adsorption capacity of 0.42 mmol/g. The synergistic effect of multi-interactions mechanisms resulted in phenolic compounds removal with adsorption energies lower than 30 kJ/mol. This prepared MCM adsorbent is promising for application in treatment of water polluted by phenols.