催化作用
过渡金属
还原(数学)
国家(计算机科学)
选择性催化还原
化学
金属
选择性还原
氧化态
化学工程
组合化学
材料科学
有机化学
计算机科学
工程类
数学
几何学
算法
作者
Shaomian Liu,Jiajian Gao,Wenqing Xu,Yongjun Ji,Tong Zhu,Guangwen Xu,Ziyi Zhong,Fabing Su
标识
DOI:10.1016/j.cej.2024.150285
摘要
The selective catalytic reduction of NO by CO (CO-SCR) is a promising technology to simultaneously eliminate the harmful NO and CO. Particularly, low-cost and efficient catalysts for CO-SCR are in high demand for industrial applications. Transition metal-based catalysts (TMCs) are highly effective for CO-SCR, as reported over the past decade. This review aims to explore the latest advancements of TMCs in the CO-SCR reaction, focusing on Fe-, Cu-, Mn-, and Co-based catalysts. By combining the theoretical calculation and experimental results, we discuss the structure-performance relationships between TMCs and CO-SCR, the reaction pathways on various catalysts, and the impact of various implementation factors, such as O2, H2O, and SO2 concentrations, along with the catalyst design strategies. Finally, the opportunities and challenges of TMCs for CO-SCR reaction are predicted and discussed.
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