硼烷
药物化学
锂(药物)
小学(天文学)
酰胺
有机化学
硼烷
试剂
区域选择性
作者
Milan Kumar Bisai,Kritika Gour,Tamal Das,Kumar Vanka,Sakya S. Sen
出处
期刊:Dalton Transactions
[The Royal Society of Chemistry]
日期:2021-02-23
卷期号:50 (7): 2354-2358
被引量:11
摘要
A selective and efficient route for the deoxygenative reduction of primary to tertiary amides to corresponding amines has been achieved with pinacolborane (HBpin) using simple and readily accessible 2,6-di-tert-butyl phenolate lithium·THF (1a) as a catalyst. Both experimental and DFT studies provide mechanistic insight.
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