聚天冬氨酸
腐蚀
聚合物
缓蚀剂
极化(电化学)
化学
电化学
环境友好型
核化学
材料科学
化学工程
吸附
朗缪尔吸附模型
冶金
有机化学
复合材料
电极
物理化学
工程类
生物
原材料
生态学
作者
Chunxiao Chai,Yanhua Xu,Ying Xu,Shanhu Liu,Lei Zhang
标识
DOI:10.1016/j.eurpolymj.2020.109946
摘要
Small-molecule organic corrosion inhibitors have attracted extensive attentions, but there are relatively few studies on corrosion inhibitors based on eco-friendly polymer materials. In the present work, dopamine modified polyaspartic acid (PASP-Dop) was well-designed and prepared. The inhibition ability of PASP-Dop towards mild steel was studied at various concentrations and temperatures using electrochemical measurement and weight-loss method. Investigations indicate that PASP-Dop has high corrosion inhibition performance for mild steel in acid solution due to the effective adsorption of PASP-Dop molecules at the metal/solution interface which is found to obey the Langmuir adsorption isotherm. From the potentiodynamic polarization measurements, the inhibition efficiency of PASP-Dop for mild steel in 0.5 M H2SO4 solution at a concentration of 100 ppm is up to 90.9% at 298 K. In addition, effect of temperature performed by weight-loss measurement reveals that PASP-Dop has good temperature adaptability. These results clearly demonstrate that as-synthesized eco-friendly polymer (PASP-Dop) is a high efficiency corrosion inhibitor with good application prospect.
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