硅
碳纤维
材料科学
化学气相沉积
锂(药物)
石墨烯
应变硅
纳米技术
化学工程
光电子学
晶体硅
复合材料
复合数
非晶硅
医学
内分泌学
工程类
作者
A. M. Wilson,B. M. Way,J. R. Dahn,T. van Buuren
摘要
Using chemical-vapor deposition nanodispersed silicon has been prepared in carbon at temperatures between 850 and 1050 °C. Samples with up to 11% atomic silicon in carbon show the same pregraphitic x-ray-diffraction pattern as those without silicon. X-ray-absorption spectroscopy shows that the silicon is bonded mostly to carbon neighbors and that large clusters of silicon are not found. It is believed that silicon atoms, or small clusters of a few silicon atoms, are located in regions of ‘‘unorganized carbon’’ which separate small regions of organized graphene layers. These materials may have application as electrode materials in advanced rechargeable lithium batteries.
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