Asymmetrische Synthese chiraler Phosphorverbindungen durch destruktiv-Oxidation von P(III)-Verbindungen mittels chiraler Oxaziridine

Asymmetric Synthesis of Chiral Phosphorus Compounds by Destructive-Selective Oxidation of P(III) Compounds by Means of Chiral Oxaziridines From camphor and fenchone chiral N -sulfonyloxaziridines (e.g, 7,13) are available that are well-suited for the destructive-stereoselective oxidation of P(III) compounds 16. Optimum reagents and reaction conditions for this oxidation are determined by a systematic study. Chiral P(III) and P(V) compounds can thus be prepared from racemic P(III) derivatives.