放电等离子烧结
材料科学
热液循环
沸石
水热合成
铯
固态
等离子体
化学工程
SPARK(编程语言)
烧结
矿物学
冶金
无机化学
物理化学
有机化学
催化作用
化学
程序设计语言
工程类
物理
量子力学
计算机科学
作者
O.O. Shichalin,Е. К. Папынов,V.A. Nepomnyushchaya,Andrei Ivanets,А.А. Белов,А. Н. Драньков,S. B. Yarusova,I. Yu. Buravlev,Anna Tarabanova,A. N. Fedorets,S.A. Azon,Zlata E. Kornakova,Sergey Y. Budnitskiy,И. Г. Тананаев,Yun Shi,Yifei Xiong,Haibo Wang
标识
DOI:10.1016/j.jeurceramsoc.2022.02.007
摘要
Hydrothermal synthesis of NaY-type zeolite was carried out and the effect of temperature on the phase composition, crystal structure, textural characteristics, particle size and morphology, as well as sorption properties to Cs + ions was studied. Solid-state matrices based on NaY zeolite the Faujasite structure containing 26.1 wt% cesium were obtained by spark plasma sintering (SPS) with high values of compressive strength (to 132.9 MPa) and Vickers microhardness to HV~ 698, Fracture toughness (K 1c ) ~ 1.26 MPa m 1/2 . The kinetics of ceramic matrices consolidation, phase composition and morphology using dilatometric studies, XRD, and SEM were studied. The thermogravimetric analysis shown the high thermal stability of the obtained samples up to 1300 °C. The high hydrolytic stability of CsAlSiO 4 ceramic was proven (leaching rate of 2.33 ×10 −8 g·cm − 2 ·day −1 and cesium diffusion coefficient De 1.41 ×10 −13 ), which exceeds the requirements of GOST R 50926–96 and ISO 6961:1982 for solid-state matrices.
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