材料科学
腐蚀
冶金
微观结构
介电谱
氢
碳化物
开裂
极化(电化学)
电化学
复合材料
化学
有机化学
电极
物理化学
作者
Janeth Marlene Quispe-Avilés,Marco Fiori,Duberney Hincapie,Oscar Maurício Prada Ramirez,Hercílio Gomes de Melo
出处
期刊:Corrosion
[NACE International]
日期:2022-06-12
卷期号:78 (8): 765-777
被引量:1
摘要
The corrosion and hydrogen-induced cracking (HIC) resistance as well as hydrogen permeation behavior of two API 5L X65 steels with different amounts of Mn and microalloying elements were compared. The corrosion behavior of both steels, evaluated using electrochemical impedance spectroscopy and polarization curves in solution A of NACE TM0284-16 standard with and without H2S saturation (sour medium), showed no relevant differences in each medium, which can be ascribed to their similar microstructures; however, the corrosion resistance of both steels was lower in the sour medium. The investigation of resistance to hydrogen-induced failures disclosed better performance for the low Mn steel. This was confirmed using a harsher HIC test performed in an HCl acidified sour medium and was ascribed to the presence of Nb carbides nanoprecipitates, as revealed by the scanning transmission electron microsccopy analysis.
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