Correlated organic–inorganic motion enhances stability and charge carrier lifetime in mixed halide perovskites

. The obtained time scales are in good agreement with experiments. Multiple phonon modes, including those of both the inorganic and organic components, couple to the electronic subsystem and accommodate the excess electronic energy lost during nonradiative charge recombination. The study reveals the unexpected atomistic mechanisms for the reduction of electron-hole recombination upon Br doping, rationalizes the experiments, and advances our understanding of the excited-state dynamics of perovskite solar cells.