材料科学
电介质
四方晶系
陶瓷
微观结构
电场
铁电性
相(物质)
相变
钙钛矿(结构)
反铁电性
储能
矿物学
分析化学(期刊)
复合材料
凝聚态物理
结晶学
光电子学
化学
热力学
物理
量子力学
功率(物理)
有机化学
色谱法
作者
Heng Wu,Wenchuan Li,Ai Hong,Zhixin Zeng,Xiaofeng Qin,Shulin Xing,Chuang Zhou,Rongli Gao,Xiaoling Deng,Wei Cai,Gang Chen,Zhenhua Wang,Xiang Lei,Chunlin Fu
标识
DOI:10.1016/j.jallcom.2021.162932
摘要
Antiferroelectric materials are considered promising energy storage materials because they have excellent energy density during the antiferroelectric phase transition. Herein, Pb0.925La0.05Zr0.95Ti0.05O3@SiO2 ([email protected]2) core-shell structure ceramic materials were synthesized by combing sol-gel method with conventional solid-phase method. The effect of holding time (3 h, 6 h, 9 h, 12 h) on the electrical properties and energy storage properties of [email protected]2 ceramics were investigated. TEM results indicate the formation of a core-shell structure. Transmission electron microscope (TEM) reveals the formation of core-shell structure. X-ray diffraction (XRD) obtained clear tetragonal perovskite structure PLZT and SiO2 phase. The phase transition temperature of [email protected]2 ceramics is between 222 °C and 225 °C, and its dielectric constant can be adjusted by the holding time. The PLZT with surface coated SiO2 can increase the breakdown electric field (BDS) and thus increase the energy density. When the holding time is 9 h, the breakdown electric field is as high as 156.84 kV/cm, and the recoverable energy density (Wre) is 1.92 J/cm3, which is mainly determined by its high density and breakdown electric field.
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