锰
纳米颗粒
吸附
铁氧体(磁铁)
人工神经网络
混合相
甲基橙
材料科学
水溶液
水介质
化学
化学工程
相(物质)
计算机科学
纳米技术
冶金
有机化学
复合材料
人工智能
工程类
催化作用
光催化
作者
Kartick Lal Bhowmik,Ajit Debnath,Ranendu Kumar Nath,Samir Chandra Das,Kalyan Kumar Chattopadhyay,Biswajit Saha
标识
DOI:10.1016/j.molliq.2016.04.009
摘要
Abstract In this study, a novel magnetic nanoscale adsorbent of mixed phase manganese ferrite and hausmannite (MNF–HM) was synthesized by a simple chemical precipitation method and its adsorptive property towards a toxic anionic dye methyl orange (MO) was investigated. This new adsorbent was characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), point of zero charge (PZC), vibrating sample magnetometer (VSM) measurements and Brunauer–Emmett–Teller (BET) analysis. These crystalline mixed phase MNF–HM nanoparticles show high saturation magnetization (30.12 emu/g) as well as high specific surface area (100.62 m 2 /g) and pore volume, which makes it a magnetically separable efficient adsorbent with maximum adsorption capacity of 303.66 mg/g for MO at room temperature. The solution pH becomes the most influencing parameter and maximum adsorption efficiency of 97.4% is observed within 45 min at solution pH 2.0 with initial MO concentration of 50 mg/L and MNF–HM nanoparticle dose of 1.0 g/L. An artificial neural network (ANN) model was developed for accurate prediction of MO removal (%) and optimal ANN structure (4–7–1) shows minimum mean squared error (MSE) of 0.00071 and high determination coefficient (R 2 ) of 0.990. Isotherm modeling exhibited that Langmuir isotherm model is the most efficient one in explaining its adsorption behavior and the kinetic studies reveal that the adsorption process follows pseudo-second-order kinetic model with the involvement of intra-particle diffusion. Thermodynamic studies reveal that the adsorption process is feasible, spontaneous and exothermic in nature.
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