电催化剂
材料科学
法拉第效率
电化学
电解质
电解
催化作用
化学工程
合金
铜
阴极
无机化学
电极
冶金
物理化学
化学
有机化学
工程类
作者
Changming Zhao,Gan Luo,Xiaokang Liu,Wei Zhang,Zhijun Li,Qian Xu,Qinghua Zhang,Huijuan Wang,Deming Liu,Fangyao Zhou,Yunteng Qu,Xiao Han,Ziqi Zhu,Geng Wu,Jing Wang,Junfa Zhu,Takeshi Yao,Yafei Li,Henny J.M. Bouwmeester,Yuen Wu
标识
DOI:10.1002/adma.202002382
摘要
Abstract Electrochemical reduction of CO to value‐added products holds promise for storage of energy from renewable sources. Copper can convert CO into multi‐carbon (C 2+ ) products during CO electroreduction. However, developing a Cu electrocatalyst with a high selectivity for CO reduction and desirable production rates for C 2+ products remains challenging. Herein, highly lattice‐disordered Cu 3 N with abundant twin structures as a precursor electrocatalyst is examined for CO reduction. Through in situ activation during the CO reduction reaction (CORR) and concomitant release of nitrogen, the obtained metallic Cu° catalyst particles inherit the lattice dislocations present in the parent Cu 3 N lattice. The de‐nitrified catalyst delivers an unprecedented C 2+ Faradaic efficiency of over 90% at a current density of 727 mA cm −2 in a flow cell system. Using a membrane electrode assembly (MEA) electrolyzer with a solid‐state electrolyte (SSE), a 17.4 vol% ethylene stream and liquid streams with concentration of 1.45 m and 230 × 10 −3 m C 2+ products at the outlet of the cathode and SSE‐containment layer are obtained.
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