瓜尔胶
核化学
溶解度
傅里叶变换红外光谱
酯交换
热重分析
质子核磁共振
自愈水凝胶
材料科学
化学
醋酸镁
有机化学
化学工程
镁
甲醇
工程类
生物化学
作者
Mazrina Mazlan,Muhammad Rizwan,Ahmad Danial Azzahari,Vidhya Selvanathan,Faridah Sonsudin,Nurshafiza Shahabudin
出处
期刊:Pigment & Resin Technology
[Emerald (MCB UP)]
日期:2021-01-04
卷期号:50 (6): 485-495
标识
DOI:10.1108/prt-06-2020-0063
摘要
Purpose The purpose of this study is to modify guar gum (GG) into guar gum acetate (GGA) and phthaloyl guar gum (PHGG) by transesterification and phthaloylation, respectively. Design/methodology/approach GG has been modified into GGA through transesterification reaction between GG and vinyl acetate and PHGG through esterification reaction with phthalic anhydride. The modified GG was characterized by solubility test, Fourier-transform infra-red (FTIR) spectroscopy, proton nuclear magnetic resonance ( 1 H NMR) spectroscopy, X-ray diffractometry (XRD) and thermogravimetric analysis. Swelling properties of GGA and PHGG hydrogels in water were evaluated. Findings These two types of modified GG have better solubility such as in dimethyl sulfoxide and N , N -dimethylformamide but no true organosolubility was achieved. The modifications were confirmed through FTIR with new absorption peaks at 1,733 cm −1 for GGA and 1,709 cm −1 for PHGG coupled with observed substitution peaks at 1.80 to 2.20 ppm and 7.40 to 7.90 ppm, respectively, from 1 H NMR spectroscopies. XRD revealed both GGA and PHGG are less crystalline than native GG. GGA was found to be more thermally stable than native GG, whereas PHGG was slightly less thermally stable than native GG. The swelling property in distilled water for native GG, PHGG and GGA was 918.43 ± 46.62%, 537.04 ± 2.87% and 393.04 ± 13.42%, respectively. Research limitations/implications The GGA and PHGG hydrogels are expected to be useful for biomedical fields such as tissue engineering and drug-delivery. Originality/value Modifications of native GG into GGA using vinyl acetate and PHGG using phthalic anhydride are novel.
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