电催化剂
过电位
材料科学
双金属片
金属有机骨架
催化作用
析氧
纳米技术
化学工程
多孔性
溶解
多金属氧酸盐
金属
电极
化学
吸附
复合材料
电化学
冶金
有机化学
物理化学
工程类
生物化学
作者
Fei‐Xiang Ma,Fucong Lyu,Yingxue Diao,Binbin Zhou,Jianghua Wu,Feiyu Kang,Zebiao Li,Xufen Xiao,Peng Wang,Jian Lü,Yang Yang Li
出处
期刊:Nano Research
[Springer Nature]
日期:2021-11-04
卷期号:15 (4): 2887-2894
被引量:13
标识
DOI:10.1007/s12274-021-3885-y
摘要
Fabrication of single-crystalline metal-organic framework (MOF) hollow nanostructures with two-dimensional (2D) morphologies is a challenging task. Herein, twin-like MOF nanobricks, a quasi-hollow 2D architecture, with multi-metal nodes and replaceable organic ligands, are uniformly and firmly grown on conductive Ni foam through a generic one-pot approach. The formation process of twin-like MOF nanobricks mainly includes selective epitaxial growth of Fe-rich MOF layer and simultaneously dissolution of the pre-formed Ni-rich metal-organic frameworks (MOFs), all of which can be ascribed to a special self-templated mechanism. The fantastic structural merits of twin-like MOF nanobrick arrays, featuring highly exposed active sites, remarkable electrical conductivity, and hierarchical porosities, enable this material for efficient electrocatalysis. Using bimetallic NiFe-MOFs grown on Ni foam as an example, the resultant twin-like nanobrick arrays can be directly utilized as three-dimensional (3D) integrated electrode for high-performance water oxidation in 1 M KOH with a low overpotential, fast reaction kinetics (28.5 mV·dec−1), and superb stability. Interestingly, the unstable NiFe-MOFs were served as an oxygen evolution reaction (OER) pre-catalyst and the single-crystalline NiFe-MOF precursor can be in-situ topochemically regulated into porous and low-crystalline NiFeOx nanosheets during the OER process. This work extends the hollowing strategy to fabricate hollow MOFs with 2D architectures and highlights their direct utilization for advanced electrocatalysis.
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