Metal/Covalent‐Organic Framework Based Cathodes for Metal‐Ion Batteries

Abstract Metal‐organic frameworks (MOFs) and covalent‐organic frameworks (COFs) are two emerging families of functional materials used in many fields. Advantages of both include compositional designability, structural diversity, and high porosity, which offer immense possibilities in the search for high‐performance electrode materials for metal‐ion batteries. A large number of MOF/COF‐based cathode materials have been reported. Despite these advantageous features and research advances, MOFs/COFs and their derivatives face various challenges as cathode materials. In this review, an overview of the progress of MOF/COF‐based cathodes for advanced metal‐ion batteries is presented, including lithium‐ion batteries and other nascent technologies, such as sodium‐ion batteries, zinc‐ion batteries, aluminum‐ion batteries, and magnesium‐ion batteries. Research advances on the cathodes of MOFs/COFs and their derivatives are summarized in terms of active sites, structural design, and protective coatings. Perspectives and directions on the future development of MOF/COF‐based cathodes are outlined for meeting the requirements of practical applications.