光催化
酒精氧化
电子顺磁共振
催化作用
化学
光化学
氧化态
降级(电信)
漫反射红外傅里叶变换
溶剂
傅里叶变换红外光谱
最先进的
氧化还原
有机化学
化学工程
生化工程
计算机科学
工程类
物理
电信
核磁共振
作者
Zewen Shen,Yang Hu,Bingfeng Li,Yingtong Zou,Shaojun Li,G. Wilma Busser,Xiangke Wang,Guixia Zhao,Martin Mühler
标识
DOI:10.1016/j.jechem.2021.03.033
摘要
Photocatalytic oxidation of alcohols has received more and more attention in recent years following the numerous studies on the degradation of pollutants, hydrogen evolution, and CO2 reduction by photocatalysis. Instead of the total oxidation of organics in the degradation process, the photo-oxidation of alcohols aims at the selective conversion of alcohols to produce carbonyl/acid compounds. Promising results have been achieved in designing the catalysts and reaction system, as well as in the mechanistic investigations in the past few years. This review summarizes the state-of-the-art progress in the photo-oxidation of alcohols, including the development of photocatalysts and cocatalysts, reaction conditions including the solvent and the atmosphere, and the exploration of mechanisms with scavengers experiment, electron paramagnetic resonance (EPR) and diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy. The challenges and outlook for the further research in this field are also discussed.
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