An Air-Rechargeable Zn/Organic Battery with Proton Storage

电池(电) 化学 阴极 电化学 电解质 有机自由基电池 氧化还原 原电池 无机化学 电极 功率(物理) 有机化学 物理化学 物理 生物化学 量子力学 细胞
作者
Zhiwei Tie,Yan Zhang,Jiale Zhu,Songshan Bi,Zhiqiang Niu
出处
期刊:Journal of the American Chemical Society [American Chemical Society]
卷期号:144 (23): 10301-10308 被引量:48
标识
DOI:10.1021/jacs.2c01485
摘要

Air-rechargeable zinc batteries are a promising candidate for self-powered battery systems since air is ubiquitous and cost-free. However, they are still in their infancy and their electrochemical performance is unsatisfactory due to the bottlenecks of materials and device design. Therefore, it is of great significance to develop creative air-rechargeable Zn battery systems. Herein, an air-rechargeable Zn battery with H+-based chemistry was developed in a mild ZnSO4 electrolyte for the first time, where benzo[i]benzo[6,7]quinoxalino[2,3-a]benzo[6,7]quinoxalino[2,3-c]phenazine-5,8,13,16,21,24-hexaone (BQPH) was employed as cathode material. In this Zn/BQPH battery, a Zn2+ coordination with adjacent C═O and C═N groups leads to an inhomogeneous charge distribution in the BQPH molecule, which induces the H+ uptake on the remaining four pairs of the C═O and C═N groups in subsequent discharge processes. Interestingly, the large potential difference between the discharged cathode of the Zn/BQPH battery and oxygen triggers the redox reaction between them spontaneously, in which the discharged cathode can be oxidized by oxygen in air. In this process, the cathode potential will gradually rise along with H+ removal, and the discharged Zn/BQPH battery can be air-recharged without an external power supply. As a result, the air-rechargeable Zn/BQPH batteries exhibit enhanced electrochemical performance by fast H+ uptake/removal. This work will broaden the horizons of air-rechargeable zinc batteries and provide a guidance to develop high-performance and sustainable aqueous self-powered systems.
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