热能储存
材料科学
熔盐
热导率
传热
纳米颗粒
热流体
热扩散率
化学工程
无定形固体
工作(物理)
体积分数
集中太阳能
复合材料
热力学
纳米技术
化学
传热系数
冶金
有机化学
物理
工程类
作者
Lei Xian,Lei Chen,Heqing Tian,Wen-Quan Tao
出处
期刊:Applied Energy
[Elsevier]
日期:2022-10-01
卷期号:323: 119555-119555
被引量:1
标识
DOI:10.1016/j.apenergy.2022.119555
摘要
• Chloride molten salt-nanoparticle composite materials were proposed and designed. • Thermal energy storage characteristics were accurately predicted by molecular dynamics simulation. • Amorphous SiO 2 greatly improves the heat transfer performance of composite materials. • A compressed interface layer is formed between the base fluid and the nanoparticles. • The compressed interface layer is mainly composed of cations and has a thickness of about 5 Å. Chloride molten salt is the most promising thermal energy storage materials for the next generation concentrated solar power (CSP) plants. In this work, to enhance the thermal performance of KNaCl 2 molten salts, composited thermal energy storage (CTES) materials based on amorphous SiO 2 nanoparticles and KNaCl 2 were proposed and designed under the guidance of the material composition design strategy. The molecular dynamics simulation method has been conducted to investigate the thermal storage properties and analyze the mechanism of heat transfer improvement from the perspective of microstructure evolution, thermal diffusion properties and energy changes. Thermal conductivity, viscosity, and specific heat capacity of CTES materials at high temperatures with different volume fractions of nanoparticles were predicted to provide reference data for the design of heat transfer systems in CSP plants. The study discovered that increasing the volume fraction of nanoparticles increases the thermal conductivity and specific heat capacity of the systems significantly, with the maximum increase of 25.28% and 7.87%, respectively. Moreover, the enhancement of heat transfer characteristics is the result of the formation of a compressed interface layer with a thickness 5 Å on the outer surface of SiO2 nanoparticles. This work has important guiding significance for the material selection and composition design of molten salt-nanoparticle composite materials used for next-generation CSP plants.
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