苯胺
配体(生物化学)
配位复合体
化学
反离子
配位聚合物
分子
结晶学
晶体结构
结晶
特里斯
锰
晶体工程
金属
高分子化学
超分子化学
离子
有机化学
受体
生物化学
作者
Ann Almesåker,Susan A. Bourne,Gaëlle Ramon,Janet L. Scott,Christopher R. Strauss
出处
期刊:CrystEngComm
[The Royal Society of Chemistry]
日期:2007-01-01
卷期号:9 (11): 997-997
被引量:18
摘要
The ligand N,N,4-tris(pyridin-2-ylmethyl)aniline was synthethised using a multicomponent reaction, which is applicable to the synthesis of a large library of similarly structured ligands. A range of metal complexes with copper, cobalt and manganese ions were crystallised as discrete complexes, dimers and 1D coordination polymers, illustrating the flexibility of the ligand in the preparation of diverse structures. While coordination about the metal centres is similar in each group with a common metal ion, the different structures represent materials with varying structural and packing topologies. Varying the counterions and crystallisation solvents gives rise to discrete complexes, dimers and a porous 1D coordination polymer. In the latter case, solvent molecules entrapped in the channels are replaceable and guest exchange is detected by single crystal and powder diffraction indicating interesting storage possibilities.
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