Selective Carbonylation of Methanol to Dimethyl Carbonate by Gas–Liquid–Solid-Phase Boundary Electrolysis

Abstract Selective and efficient electrochemical carbonylation of MeOH to DMC was performed over PdCl2/VGCF (vapor grown carbon fiber) anode by utilizing the three-phase boundary electrolysis at 1 atm (CO) and 298 K.