Synthesis of α-acetoxy and formyloxy ketones by thallium(III) promoted α-oxidation
药物化学
酮
催化作用
试剂
作者
Jong Chan Lee,Yong Suk Jin,Ju-Hee Choi
出处
期刊:Chemical Communications [The Royal Society of Chemistry] 日期:2001-01-01卷期号: (11): 956-957被引量:48
标识
DOI:10.1039/b102192n
摘要
Treatment of ketones with thallium(III) triflate in
amide solvents at 60 °C for 30 min followed by addition of small
amounts of H2O cleanly provided the corresponding
α-acyloxy ketones.