化学
嬉戏
复分解
烷基
降冰片烯
烯烃
吡啶
反应性(心理学)
聚合
药物化学
开环复分解聚合
有机化学
高分子化学
组合化学
催化作用
医学
替代医学
病理
聚合物
作者
Parami Gunasekera,Sanchita Paul,Samantha N. MacMillan,David C. Lacy
标识
DOI:10.1002/ejic.202300757
摘要
Neutral three‐coordinate iron alkylidenes of the form PN‐Fe=CHR have been proposed as viable candidates for alkene metathesis. Indeed, during the final stages of preparing this current study, a separate report disclosed that dearomatized PN‐Fe‐alkyl complexes are active precatalysts for ring‐opening metathesis polymerization (ROMP) of norbornene implicating PN‐Fe=CHR species as possible intermediates. In yet another separate report, we prepared Zn analogues of PN‐Fe‐alkyl complexes and herein provide an account for the synthesis, characterization, and reactivity of some new iron complexes with the same tBu substituted PN platform.
科研通智能强力驱动
Strongly Powered by AbleSci AI