材料科学
电介质
复合材料
石墨烯
三元运算
复合数
高-κ电介质
陶瓷
微观结构
介电损耗
纳米技术
光电子学
计算机科学
程序设计语言
作者
Wen-Ning Qi,Liuyang Li,Ruolin Han,Yuhan Hou,Zheng Zhou,Guangxin Chen,Qifang Li
出处
期刊:ACS omega
[American Chemical Society]
日期:2024-03-07
标识
DOI:10.1021/acsomega.3c10111
摘要
Using high-dielectric inorganic ceramics as fillers can effectively increase the dielectric constant of polymer-based composites. However, a high percentage of fillers will inevitably lead to a decrease in the mechanical toughness of the composite materials. By introducing high aspect ratio copper calcium titanate (CaCu3Ti4O12) nanowires (CCTO NWs) and graphene as fillers, the ternary poly(vinylidene fluoride) (PVDF)-based composites (CCTO NWs-graphene)/PVDF with a significant one-dimensional orientation structure were prepared by hot stretching. CCTO NWs and graphene are arranged in a directional manner to form a large number of microcapacitor structures, which significantly improves the dielectric constant of the composites. When the ratio of CCTO NWs and graphene is 0.2 and 0.02, the oriented composites have the highest dielectric constant, which is 19.3% higher than the random composites, respectively. Numerical simulations reveal that the introduction of graphene and the construction of the one-dimensional oriented microstructure have a positive effect on improving the dielectric properties of the composites. This study provides a strategy to improve the dielectric properties of composite materials by structural design without changing the filler content, which has broad application prospects in the field of electronic devices.
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